Table of VSEPR Shapes

Valence Shell Electron Pair Repulsion model shapes, listed by number of bonds. Rows are colored according to the total number of electron domains.

  Number of Bonds on Central Atom
1 2 3 4 5 6
Number of
Lone Pairs on
Central Atom
0 Linear Linear Trigonal
Planar
Tetrahedral Trigonal
Bipyramidal
Octahedral
1 Linear Bent Trigonal Pyramidal See-saw Square Pyramidal
2 Linear Bent T-Shaped Square Planar
3 Linear Linear

Bonding
Electron
Domains
Lone
Pair
Domains
Total
Electron
Domains
Shape Ideal
Bond
Angle(s)
Examples Image
1 0, 1, 2, or 3 1, 2, 3, or 4 linear none H2, N2, O2, CO, CN Linear-1Bonds.0Lone.Pairs (4K)Linear-1Bonds.0Lone.Pairs (4K)
2 0 2 linear 180° BeCl2, CO2 Linear-2Bonds.0Lone.Pairs (22K)Linear-2Bonds.0Lone.Pairs (22K)
2 1 3 bent 120° SO2, NO2 Bent-2Bonds.1Lone.Pair (30K)Bent-2Bonds.1Lone.Pair (30K)
2 2 4 bent 109.5° H2O, SCl2, NH2 Bent-2Bonds.2Lone.Pairs (19K)Bent-2Bonds.2Lone.Pairs (19K)
2 3 5 linear 180° XeF2 Linear-2Bonds.3Lone.Pairs (21K)Linear-2Bonds.3Lone.Pairs (21K)
3 0 3 trigonal planar 120° BF3, AlCl3, CO32–, H2CO, NO3 Trigonal.Planar-3Bonds.0Lone.Pairs (30K)Trigonal.Planar-3Bonds.0Lone.Pairs (30K)
3 1 4 trigonal pyramidal 109.5° NH3, PCl3, ClO3, H3O+ Trigonal.Pyramidal-3Bonds.1Lone.Pair (18K)Trigonal.Pyramidal-3Bonds.1Lone.Pair (18K)
3 2 5 T-shaped 90°, 180° ClF3, BrF3 T-shaped-3Bonds.2Lone.Pairs (14K)T-shaped-3Bonds.2Lone.Pairs (14K)
4 0 4 tetrahedral 109.5° CH4, SiCl4, ClO4, SO42– Tetrahedral-4Bonds.0Lone.Pairs (11K) Tetrahedral-4Bonds.0Lone.Pairs (11K)
4 1 5 see-saw 180°, 120° SF4, SeF4, IO2F2, ClF4+ See-saw-4Bonds.1Lone.Pair (9K) See-saw-4Bonds.1Lone.Pair (9K)
4 2 6 square planar 90° XeF4, PtCl42– Square.Planar-4Bonds.2Lone.Pairs (10K) Square.Planar-4Bonds.2Lone.Pairs (10K)
5 0 5 trigonal bipyramidal 90°, 120° PCl5, PF3Cl2, SbF5 Trigonal.Bipyramidal-5Bonds.0Lone.Pairs (25K) Trigonal.Bipyramidal-5Bonds.0Lone.Pairs (25K)
5 1 6 square pyramidal 90° IF5, BrF5, XeOF4 Square.Pyramidall-5Bonds.1Lone.Pair (13K) Square.Pyramidall-5Bonds.1Lone.Pair (13K)
6 0 6 octahedral 90° SF6, Fe(CN)63– Octahedral-6Bonds.0Lone.Pairs (21K) Octahedral-6Bonds.0Lone.Pairs (21K)



page break
 
Bonding
Electron
Domains
Lone
Pair
Domains
Total
Electron
Domains
Shape Ideal
Bond
Angle(s)
Examples Image
1 0, 1, 2, or 3 1, 2, 3, or 4 linear none H2, N2, O2, CO, CN Linear-1Bonds.0Lone.Pairs (4K)Linear-1Bonds.0Lone.Pairs (4K)
2 0 2 linear 180° BeCl2, CO2 Linear-2Bonds.0Lone.Pairs (22K)Linear-2Bonds.0Lone.Pairs (22K)
3 0 3 trigonal planar 120° BF3, AlCl3, CO32–, H2CO, NO3 Trigonal.Planar-3Bonds.0Lone.Pairs (30K)Trigonal.Planar-3Bonds.0Lone.Pairs (30K)
2 1 3 bent 120° SO2, NO2 Bent-2Bonds.1Lone.Pair (30K)Bent-2Bonds.1Lone.Pair (30K)
4 0 4 tetrahedral 109.5° CH4, SiCl4, ClO4, SO42– Tetrahedral-4Bonds.0Lone.Pairs (11K) Tetrahedral-4Bonds.0Lone.Pairs (11K)
3 1 4 trigonal pyramidal 109.5° NH3, PCl3, ClO3, H3O+ Trigonal.Pyramidal-3Bonds.1Lone.Pair (18K)Trigonal.Pyramidal-3Bonds.1Lone.Pair (18K)
2 2 4 bent 109.5° H2O, SCl2, NH2 Bent-2Bonds.2Lone.Pairs (19K)Bent-2Bonds.2Lone.Pairs (19K)
5 0 5 trigonal bipyramidal 90°, 120° PCl5, PF3Cl2, SbF5 Trigonal.Bipyramidal-5Bonds.0Lone.Pairs (25K) Trigonal.Bipyramidal-5Bonds.0Lone.Pairs (25K)
4 1 5 see-saw 180°, 120° SF4, SeF4, IO2F2, ClF4+ See-saw-4Bonds.1Lone.Pair (9K) See-saw-4Bonds.1Lone.Pair (9K)
3 2 5 T-shaped 90°, 180° ClF3, BrF3 T-shaped-3Bonds.2Lone.Pairs (14K)T-shaped-3Bonds.2Lone.Pairs (14K)
2 3 5 linear 180° XeF2 Linear-2Bonds.3Lone.Pairs (21K)Linear-2Bonds.3Lone.Pairs (21K)
6 0 6 octahedral 90° SF6, Fe(CN)63– Octahedral-6Bonds.0Lone.Pairs (21K) Octahedral-6Bonds.0Lone.Pairs (21K)
5 1 6 square pyramidal 90° IF5, BrF5, XeOF4 Square.Pyramidall-5Bonds.1Lone.Pair (13K) Square.Pyramidall-5Bonds.1Lone.Pair (13K)
4 2 6 square planar 90° XeF4, PtCl42– Square.Planar-4Bonds.2Lone.Pairs (10K) Square.Planar-4Bonds.2Lone.Pairs (10K)
Here is a page with only up to four bonds for VSEPR shapes.
Here is the old version of this page
Last updated: Jan 09, 2023       Home